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SiliaBond® Pyridinium Dichromate nec (PDC)

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SiliaBond® Pyridinium Dichromate nec (PDC)

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Product Number Quantity  
R24530B-5g 5 g

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R24530B-10g 10 g

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R24530B-25g 25 g

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R24530B-50g 50 g

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R24530B-100g 100 g

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R24530B-250g 250 g

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R24530B-500g 500 g

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R24530B-1kg 1 kg

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Product Description

Specifications


 
  • Details

    SiliaBond® Pyridinium Dichromate (Si-PDC) may be used as an alternative to Si-PCC in nucleoside and carbohydrate oxidation, particularly for fragile molecules.SiliaBond PDC can also be used in conjunction with tertbutylhydroperoxide for a variety of oxidative transformations.2

    PDC immobilized onto silica is a very convenient and effective reagent for oxidizing allylic and benzylic alcohols, saturated primary and secondary alcohols, and is compatible with acid-sensitive groups, such as cyclopropane ring or ketal function.3

    Oxidation of 4-tert-butylcyclohexanol to 4-tert-butylcyclohexanone with 2 eq. of Si-PDC in anhydrous DCM at room temperature is complete after 6 hours.

    PRODUCT SPECIFICATIONS

    MSDS-R24530B

    APPLICATION NOTE
    Oxidation of Alcohols

    RELATED PUBLICATIONS

    1. J. Chem. Soc. Perkin Trans. I, (1982) 1967
    2. J. Chem. Soc. Chem. Commun., 7 (1993) 651
    3. Tetrahedron, 35 (1979) 1789
  • Additional Information

    Array Pyridinium Dichromate (PDC)
    Family / Formats SiliaBond® (Functionalized Silicas)
    Particle Size 40-63 µm / 230-400 mesh
    Pore Size 60 Å
    Endcapping Non-endcapped
    Storage Condition Keep dry and cool (<8°C)