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SiliaMetS Thiol in the Synthesis of Polymer Films for Measurement of Optical Properties

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An asymmetric bifunctional monomer having both an unprotected alkynyl group and a vinyl ether (VE) polymerization of VEEP smoothly proceeded in a controlled manner under a living cationic polymerization condition to give alkyne-substituted polyVE (poly-VEEP) without any protection of the pendant alkynyl function.

In the click reaction of precursor macromonomer MA-PVEEP (scheme), the resultant polymer MA-P(VE-Mal) was purified from contaminating copper with SiliaMetS Imidazole.

Minoda, M. et al. J. Polym Sc. Part A. Polym. Chem., 2018, 1

 

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  1. SiliaMetS Imidazole (IMI) (R79230B)

    SiliaMetS Imidazole (IMI) (R79230B)

    SiliaMetS Imidazole (Si-IMI) is a versatile metal scavenger for a variety of metals under a wide range of conditions and the preferred metal scavenger for iron catalysts. Best scavenger for: Cd, Co, Cu, Fe, Ir, Li, Mg, Ni, Os, W & Zn. Good scavenger for: Cr, Pd & Rh. It can also be used as an amine base in systems that are generally sensitive to basic conditions compared to other SiliaMetS supported bases.

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