Follow SiliCycle on Facebook Follow SiliCycle on Twitter Follow SiliCycle on LinkedIn Watch our videos on Youtube

SiliaBond Carbamate (CAR) (R50130B)

Availability: In stock

Add to Cart

SiliaBond Carbamate (CAR) (R50130B)

Prices do not include applicable taxes, customs, duties and/or shipping.

Product Number Quantity  
R50130B-5g 5 g

You need to be logged-in to order & view product price

R50130B-10g 10 g

You need to be logged-in to order & view product price

R50130B-25g 25 g

You need to be logged-in to order & view product price

R50130B-50g 50 g

You need to be logged-in to order & view product price

R50130B-100g 100 g

You need to be logged-in to order & view product price

R50130B-250g 250 g

You need to be logged-in to order & view product price

R50130B-500g 500 g

You need to be logged-in to order & view product price

R50130B-1kg 1 kg

You need to be logged-in to order & view product price

Product Description

Specifications


 
  • Details

    SiliaBond® Carbamate (CAR) is a versatile scavenger for nucleophiles. It readily scavenges amines, thiols, thiolates, alcohols, alkoxides, and acidic phenols. Loading is determined by the removal of benzylamine in hexane at room temperature.

    Si-CAR has been used to scavenge amines in a "cap-tag" methodology for oligosaccharide preparation by automated solid phase synthesis1 and in the preparation of 2,5-diketopiperazines and 1,4-benzodiazepine-2,5-diones.2

    Silica supported Carbamate has superior reactivity in a broader range of solvents when compared to polymer-based materials.

    RELATED PUBLICATIONS

    1. Angew. Chem. Int. Ed., 40 (2001) 4433
    2. Org. Lett., 4 (2002) 1167
  • Additional Information

    Array Carbamate
    Family / Formats SiliaBond® (Functionalized Silicas)
    Particle Size 40 - 63 µm / 230 - 400 mesh
    Pore Size 60 Å
    Endcapping Endcapped
    Storage Condition Keep dry and cool (<8°C)